18 research outputs found
A matrix interpolation between classical and free max operations: I. The univariate case
Recently, Ben Arous and Voiculescu considered taking the maximum of two free
random variables and brought to light a deep analogy with the operation of
taking the maximum of two independent random variables. We present here a new
insight on this analogy: its concrete realization based on random matrices
giving an interpolation between classical and free settings.Comment: 14 page
Global spectrum fluctuations for the -Hermite and -Laguerre ensembles via matrix models
We study the global spectrum fluctuations for -Hermite and
-Laguerre ensembles via the tridiagonal matrix models introduced in
\cite{dumitriu02}, and prove that the fluctuations describe a Gaussian process
on monomials. We extend our results to slightly larger classes of random
matrices.Comment: 43 pages, 2 figures; typos correcte
Functional limit theorems for random regular graphs
Consider d uniformly random permutation matrices on n labels. Consider the
sum of these matrices along with their transposes. The total can be interpreted
as the adjacency matrix of a random regular graph of degree 2d on n vertices.
We consider limit theorems for various combinatorial and analytical properties
of this graph (or the matrix) as n grows to infinity, either when d is kept
fixed or grows slowly with n. In a suitable weak convergence framework, we
prove that the (finite but growing in length) sequences of the number of short
cycles and of cyclically non-backtracking walks converge to distributional
limits. We estimate the total variation distance from the limit using Stein's
method. As an application of these results we derive limits of linear
functionals of the eigenvalues of the adjacency matrix. A key step in this
latter derivation is an extension of the Kahn-Szemer\'edi argument for
estimating the second largest eigenvalue for all values of d and n.Comment: Added Remark 27. 39 pages. To appear in Probability Theory and
Related Field
Regioisomeric and substituent effects upon the outcome of the reaction of 1-borodienes with nitrosoarene compounds
A study of the reactivity of 1-borodienes with nitrosoarene compounds has been carried out showing an outcome that differs according to the hybridization state of the boron moiety. Using an sp2 boron substituent, a one-pot hetero-Diels–Alder/ring contraction cascade occurred to afford N-arylpyrroles with low to good yields depending on the electronic properties of the substituents on the borodiene, whereas an sp3 boron substituent led to the formation of stable boro-oxazines with high regioselectivity in most of the cases, in moderate to good yields. 1H and 11B NMR studies on two boro-oxazine regioisomers showed that selective deprotection can be performed. Formation of either the pyrrole or the furan derivative is pH- and regioisomer-structure-dependent. The results obtained, together with previous B3LYP calculations, support mechanistic proposals which suggest that pyrrole, or furan, formation proceeds via oxazine formation, followed by a boryl rearrangement and an intramolecular addition–elimination sequence